(2,2′-Bipyridine-κ2 N,N′)bis(N-ethyl-N-methyldithiocarbamato-κ2 S,S′)zinc(II)
نویسندگان
چکیده
The complete mol-ecule of the title compound, [Zn(C(4)H(8)NS(2))(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C-C bond of the 2,2'-bipyridine mol-ecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN(2)S(4) octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)bis(4-methylbenzoato-κ2 O,O′)zinc(II)
In the title compound, [Zn(C(8)H(7)O(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by four O atoms from two chelating 4-methyl-benzoate ligands and two N atoms from a 2,2'-bipyridine ligand, displaying a disordered octahedral geometry. C-H⋯O hydrogen bonds connect the complex mol-ecules into a three-dimensional supra-molecular structure.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010